In order to study the salt precipitation law of the NaCl?Na2SO4?H2O ternary system at a temperature of 298.15 K, the Pitzer model was used to predict and calculate the activity coefficient and solubility of the system, and the variation of the activity coefficients of Na+, Cl- and SO
and the corresponding phase diagram of the ternary system were analyzed. The results show that with the increase of the Na2SO4 mass fraction, the activity coefficients of Cl- and SO
have no obvious change, while the activity coefficient of Na+ icreases first and then decreases. When the mass fraction of Na2SO4 in the liquid phase is less than 6.8%, the average change rate of the increase in the activity coefficient of Na+ is 4.4%. When the mass fraction of Na2SO4 in the liquid phase is between 6.8% and 14.9%, the average change rate of decrease in the activity coefficient of Na+ is 4.1%, when the mass fraction of Na2SO4 in the liquid phase reaches 14.9%, the activity coefficient of Na+ decreases fastest, and the average change rate is 8.0%; when the mass fraction of NaCl in the liquid phase is greater than 22.9% and the mass fraction of Na2SO4 is less than 6.8% ,as the water evaporates, NaCl precipitates first and Na2SO4 precipitates later; when the liquid phase mass fraction of NaCl is 14.0%~22.9% and the mass fraction of Na2SO4 is 6.8%~14.9%, the precipitation order is reversed.